Where did you get the information that Mary Ann E. Pouncey was born 1825? I have a record showing the purchase of land in Clarke County, AL on 8/11/1836 by a Mary Ann Pouncey. Another record shows the marriage of Mary Ann Pouncey in Clarke County in 1846 to William B. Larrimore. I have assumed that these two Clarke County Mary Ann's were one and the same, but the purchase of land in 1836 would not fit well with a birth year of 1825. Have also assumed that Mary Ann E. Pouncey was the same individual, and that her parents were James Nathaniel and Elizabeth Pouncey. James Nathaniel was the son of Samuel, younger brother of Roger. Roger and Samuel were sons of Anthony and Lucy.
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