I don't have anything specific on William R. Puryear but if you go to John Puryear's web site, http://familytreemaker.genealogy.com/users/p/u/r/John-L-Puryear/index.html and scroll down to the Descendants of Samuel Puryear, you may be able to find information on William. I have a James Puryear ancestor who was born in Mecklenburg Co. Va. in 1803.
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